7380-79-2 → HCID 18982460、化合物

HRID 1440888ノート

反応式

HRID 1440888 の反応式
[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4].[Li+].[Cl-].[CH3:26][S+:27]([CH3:37])[CH2:28]C(C1C=CC=CC=1)=O>O>[CH3:26][S+:27]([CH3:37])[CH2:28][C:18]1[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=1.[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:6]1[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=1)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[CH2:2][CH2:3][CH3:4]

参加物

4

反応物 2

HCID 218810807380-79-2HCID 23668465HCID 23668465、化合物

生成物 1

HCID 18982460HCID 18982460、化合物収率 181.8%

試薬・触媒・溶媒 1

HCID 962Water溶媒2 回

実験手順

An aqueous solution of 10.11 g of lithium butyltriphenylborate in 100 ml of water was added to an aqueous solution of 6.24 g of dimethylphenacylsulfonium chloride in 150 ml of water, and the resultant mixture was stirred at room temperature for 30 minutes. The reaction mixture was filtered, and the resultant crystal was washed with water and dried to give 13.58 g of dimethylbenzylsulfonium-butyltriphenylborate as a white crystal.

後処理

  1. filtrationThe reaction mixture was filtered
  2. washthe resultant crystal was washed with water
  3. customdried

出典と根拠

ORDレコード
ord-7fe3501b7f8c4eedb342298a10db1768
出典データセット
uspto-grants-1996_03
特許番号
US05500453

反応ノート

読み込み中…