1,1-Bis(methylthio)-2-nitroethylene → 2-(Nitromethylene)-1-((tetrahydrofuran-3-yl)methyl)imidazolidine
反応式
CS[C:3](SC)=[CH:4][N+:5]([O-:7])=[O:6].[O:10]1[CH2:14][CH2:13][CH:12]([CH2:15][NH:16][CH2:17][CH2:18][NH2:19])[CH2:11]1>C(O)C>[N+:5]([CH:4]=[C:3]1[NH:19][CH2:18][CH2:17][N:16]1[CH2:15][CH:12]1[CH2:13][CH2:14][O:10][CH2:11]1)([O-:7])=[O:6]参加物
4
反応条件
- 温度
- 85 °C
実験手順
2.5 g (0.0178 mol) of 1,1-dimethylthio-2-nitroethene, 2.56 g (0.0178 mol) of N1-((tetrahydrofuran-3-yl)methyl)ethane-1,2-diamine were added to 50 ml of ethanol. The resulting mixture was heated under reflux for 8 hours at 80-90 ° C. The mixture was then cooled to educe solid, concentrated, filtrated and dried to give a light yellow powder in 81% yield.
後処理
- temperatureThe resulting mixture was heated
- temperatureThe mixture was then cooled
- concentrationconcentrated
- filtrationfiltrated
- customdried
- customto give a light yellow powder in 81% yield
出典と根拠
- ORDレコード
- ord-e5ce06ae61b443f3858006c68e49ba9c
- 出典データセット
- uspto-grants-2010_02
- 特許番号
- US07655665B2
反応ノート
読み込み中…