Hydrogen Peroxide → HCID 59169122、化合物

反応式

[CH2:1]([O:4][CH2:5][CH2:6][C:7]([OH:9])=[O:8])[CH2:2]C.OO.S(=O)(=O)(O)[OH:13].[I-].[K+].S([O-])([O-])(=O)=S.[Na+].[Na+].C(OO)=O>>[CH2:1]([O:4][CH2:5][CH2:6][C:7]([O:9][OH:13])=[O:8])[CH3:2]

参加物

反応物 5

HCID 784Hydrogen Peroxide

HCID 1118Sulfuric Acid

HCID 66051Performic Acid

HCID 150334603-Propoxypropanoic acid

HCID 21461527HCID 21461527、化合物

生成物 1

HCID 59169122HCID 59169122、化合物

実験手順

3-Propoxypropionic acid (25.0 g, 189 mmol) was added with 50% aqueous hydrogen peroxide (16.4 mL, 284 mmol) and concentrated sulfuric acid (0.5 mL, 9.4 mmol) and left at room temperature for 4 days. Potassium iodide/sodium thiosulfate titration as described in Example 1 was conducted to determine the concentration of peroxycarboxylic acid 3 (Compound 3) after the 4 days.