Ethanol → 3-Ethoxy-5-(2-hydroxyphenyl)-2-cyclohexenone

HRID 1446980ノート

反応式

HRID 1446980 の反応式
[OH:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[CH:8]1[CH2:13][C:12](=[O:14])[CH2:11][C:10](=[O:15])[CH2:9]1.O.[CH2:17](O)[CH3:18]>>[CH2:17]([O:14][C:12]1[CH2:13][CH:8]([C:3]2[CH:4]=[CH:5][CH:6]=[CH:7][C:2]=2[OH:1])[CH2:9][C:10](=[O:15])[CH:11]=1)[CH3:18]

参加物

4

反応物 3

HCID 702EthanolHCID 962WaterHCID 176065765-(2-Hydroxyphenyl)cyclohexane-1,3-dione

生成物 1

HCID 205521353-Ethoxy-5-(2-hydroxyphenyl)-2-cyclohexenone

実験手順

5-(2-Hydroxyphenyl)-1,3-cyclohexanedione (5.0 g) was dissolved in ethanol (225 ml). The solution was heated under reflux for 3h and diluted to 2 l. by the addition of water. The solid which separated out was collected by filtration, washed with water and dried. Recrystallisation from ethanol afforded the title compound (1.5 g) as pale yellow prisms m.p. 194°-197°.

後処理

  1. temperatureThe solution was heated
  2. additiondiluted to 2 l
  3. customThe solid which separated out
  4. filtrationwas collected by filtration
  5. washwashed with water
  6. customdried
  7. customRecrystallisation from ethanol

出典と根拠

ORDレコード
ord-169f25352850496cae9791a9bef394ff
出典データセット
uspto-grants-1982_02
特許番号
US04315006

反応ノート

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