Acetic Anhydride → HCID 54524075、化合物
反応式
[CH3:1][N:2]([CH3:16])[CH:3]=[C:4]([C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][C:8]=1[N+:13]([O-:15])=[O:14])[CH:5]=O.[N+:17]([CH2:20][C:21]([O:23][CH3:24])=[O:22])([O-:19])=[O:18].C(OC(=O)C)(=O)C>>[CH3:24][O:23][C:21](=[O:22])[C:20]([N+:17]([O-:19])=[O:18])=[CH:5][C:4]([C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][C:8]=1[N+:13]([O-:15])=[O:14])=[CH:3][N:2]([CH3:16])[CH3:1]参加物
4
実験手順
A mixture of 63.0 g (0.29 mol) of the compound of Example 14 and 35.7 g (0.30 mol) of methyl nitroacetate in 600 ml. of acetic anhydride was heated at 85° for 2 hours. The resulting product was worked up and recrystallized from benzene-DMF (2:1) affording 74.9 g (81%) of product as red orange crystals, m.p. 211°-214°.
後処理
- customrecrystallized from benzene-DMF (2:1)