1-Decanol → Magnesium decanolate

HRID 1447774ノート

反応式

HRID 1447774 の反応式
C([O-])(C)C.[Mg+2:5].C([O-])(C)C.[Mg].[CH2:11]([OH:21])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20]>C(O[Ti](OCCCC)(OCCCC)OCCCC)CCC.C(O)(C)C>[CH2:11]([O-:21])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20].[CH2:11]([O-:21])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20].[Mg+2:5]

参加物

6

反応物 3

HCID 81741-DecanolHCID 5462224Magnesium2 回HCID 10197750Magnesium dipropan-2-olate

生成物 1

HCID 21149434Magnesium decanolate

試薬・触媒・溶媒 2

HCID 178454852HCID 178454852、化合物触媒HCID 3776Isopropanol溶媒

実験手順

If magnesium isopropanolate, together with e.g., 20 moles % of tetrabutoxy titanium, with respect to the amount of magnesium, and one or two equivalents of decanol, is introduced into an organic solvent, and the mixture is heated, a desirably low-viscosity solution of magnesium isopropanolatedecanolate, and/or of magnesium didecanolate, is formed, from which the liberated isopropanol can now readily be evaporated so as to achieve substantially full completion of the reaction.

後処理

  1. temperaturethe mixture is heated

出典と根拠

ORDレコード
ord-e1e9c9fb7ba042fb99b0bb40dead3839
出典データセット
uspto-grants-1979_12
特許番号
US04178300

反応ノート

読み込み中…