Methyl Chloride → HCID 20351236、化合物

反応式

[CH2:1]([P:9]([CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])[CH2:10][CH3:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[CH3:20][Cl:21]>>[Cl-:21].[CH2:12]([P+:9]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])([CH2:10][CH3:11])[CH3:20])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19]

参加物

反応物 2

HCID 6327Methyl Chloride

HCID 22497600HCID 22497600、化合物

生成物 1

HCID 20351236HCID 20351236、化合物

実験手順

Into 14.4 g (0.05 m) of dioctyl ethyl phosphine, placed in the bubbler reactor described in Example 2, methyl chloride was introduced at 130° C. for 4 hours. The degree of weight gain observed corresponded to a quantitative formation of the desired product; a colorless, waxy solid at room temperature. In the nmr spectrum of this product, the α-meythyl doublet appears at 1.93 ppm (JP-C 14 cps).

後処理

additionwas introduced at 130° C. for 4 hours

出典と根拠

ORDレコード: ord-4cb773b668114df29a1b317fbb2a8713
出典データセット: uspto-grants-1980_02
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04188380

反応ノート

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