Catechol → HCID 131719865、化合物

HRID 1451992

反応式

HRID 1451992 の反応式
[C:1]1([C:3](=[CH:5][CH:6]=[CH:7][CH:8]=1)O)[OH:2].[NH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][NH2:22].[O:23]=O>ClCC(Cl)CCl.ClC=C(Cl)Cl>[C:16]1([C:5]2[C:6](=[O:23])[CH:7]=[CH:8][C:1](=[O:2])[CH:3]=2)[CH:17]=[CH:18][CH:19]=[CH:20][CH:21]=1.[NH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][NH2:22]

参加物

6

反応物 3

HCID 289CatecholHCID 977Oxygen2 回HCID 177271,12-Dodecanediamine

生成物 1

HCID 131719865HCID 131719865、化合物

試薬・触媒・溶媒 2

HCID 6575Trichloroethylene溶媒2 回HCID 72851,2,3-Trichloropropane溶媒

実験手順

About 14.54 g (0.0782 mol) 2-phenyl-hydrooquinone, about 0.2 g (0.0018 mol) catechol (chemical name 1,2-dihydroxybenzene) and about 16 g (0.08 mol) 1,12diaminododecane were dissolved in a solvent mixture comprising of about 30 mL of 1,2,3trichloropropane and 60 mL of trichloroethylene. Oxygen was then passed at a flow rate of about 50 cc/min through the solution for about one hour. About 0.2 g of cupric sulfate was then added to the reaction mixture. Oxygen flow was reinstated for about an additional two hours. At the end of the polymerization reaction most of the trichloroethylene was removed under high vacuum, without raising the temperature above 35° C. This solution of poly-(2-phenyl-benzoquinone-1,12-diaminododecane) polymer can be used directly for coating purposes.

後処理

  1. customwas reinstated for about an additional two hours
  2. customwas removed under high vacuum
  3. temperaturewithout raising the temperature above 35° C

出典と根拠

ORDレコード
ord-abe3001167674f86ba1595956f75f223
出典データセット
uspto-grants-1997_02
特許番号
US05606010

関連ノート

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