化工社化工社 化学情報印刷レポート · 研究参考用
1,1,3,3,3-Pentafluoro-1,2,2-trichloropropane → 1,1,3,3,3-Pentafluoro-1,2,2-trichloropropane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1,1,3,3,3-Pentafluoro-1,2,2-trichloropropane | HCID 15335 | — |
| 反応物 | HCID 178418361 | HCID 178418361 | — |
| 触媒 | Palladium | HCID 23938 | — |
| 生成物 | 1,1,3,3,3-Pentafluoro-1,2,2-trichloropropane | HCID 15335 | — |
| 生成物 | 1,1,3,3,3-Pentafluoropropene | HCID 69647 | — |
| 生成物 | 2-Chloro-1,1,3,3,3-pentafluoropropene | HCID 102335 | — |
反応手順
The test procedure described in Example 2 was repeated except that the catalyst was 0.5% Pd on alumina, the reaction temperature was held to approximately 150° C. and the duration of the test was approximately 12.6 hours. The mole ratio of hydrogen to CF3CCl2CF2Cl introduced into the quartz reactor was approximately 1.09. The reaction product was collected and its composition was determined. The reaction resulted in a conversion of CF3CCl2CF2Cl of about 97.8%, with a selectivity for CF3CH═CF2 of 6.8%, for CF3CCl═CF2 of 85.4%, and for CF3CHClCF2Cl of 3.8%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07473810B1 |
| 出典データセット | uspto-grants-2009_01 |
| ORD ID | ord-9c1f5536aa5a4b74831899f17f28734d |
| 出典メモ | uspto-grants-2009_01 |