N,N-Dimethyl-N-decylamine → N-(4-vinylbenzyl)-N-decyl-N,N-dimethylammonium chloride
反応式
[CH3:1][N:2]([CH3:13])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[CH:14]([C:16]1[CH:23]=[CH:22][C:19]([CH2:20][Cl:21])=[CH:18][CH:17]=1)=[CH2:15]>CCOCC>[Cl-:21].[CH:14]([C:16]1[CH:23]=[CH:22][C:19]([CH2:20][N+:2]([CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])([CH3:1])[CH3:13])=[CH:18][CH:17]=1)=[CH2:15]参加物
4
実験手順
Dimethyl decyl amine (9.30 g, 50 mmol) and 4-vinylbenzylchloride (7.63 g, 50 mmol) were added to ether (20 mL) and were allowed to stir for 12 hours. A yellow solid precipitated and was subsequently collected by filtration resulting in 3 g (17% yield). The ether was removed and the remaining solution was allowed to react neat for 24 hours giving a near quantitative yield after washing with ether. Subsequent reactions were performed neat. 1H-NMR (90 MHz, CDCl3, δ): 7.68-7.38 (dd, 4H); 6.87-6.56 (dd, 1H); 5.89-5.70 (d, 1H); 5.41-5.29 (d, 1H); 5.09 (s, 2H); 3.51 (bs, 2H); 3.31 (s, 6H); 1.81 (bs, 2H) 1.25 (bs, 14H); 0.92-0.81 (t, 3H).