Biphenyl → Silane, trichloro(9H-fluoren-9-ylmethyl)-

HRID 1457371

反応式

HRID 1457371 の反応式
[Al].[C:2]1([C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.Cl[CH:15]([Si:18]([Cl:21])([Cl:20])[Cl:19])[CH2:16]Cl>CCCCCC>[Cl:19][Si:18]([CH2:15][CH:16]1[C:13]2[CH:12]=[CH:11][CH:10]=[CH:9][C:8]=2[C:2]2[C:7]1=[CH:6][CH:5]=[CH:4][CH:3]=2)([Cl:21])[Cl:20]

参加物

5

反応物 3

HCID 7095BiphenylHCID 79093Silane, trichloro(1,2-dichloroethyl)-HCID 5359268Aluminum

生成物 1

HCID 12065632Silane, trichloro(9H-fluoren-9-ylmethyl)-収率 38.9%

試薬・触媒・溶媒 1

HCID 8058Hexane溶媒2 回

実験手順

In a 250 ml, three-necked, frame dried, round bottom flask, aluminum 0.40 g (15 mmol), biphenyl 20.0 g (130 mmol), and (1,2-dichloroethyl)- trichlorosilane 7.50 ml (53.5 mmol) were reacted as in Example 1 at 120° C. for 30 min. Freshly distilled hexane (60 ml) was added to the reaction mixture and insoluble solids in hexane were filtered from the organic solution. After hexane was distilled, the reaction products were vacuum distilled to give 6.53 g of 9-(trichlorosilyl)methylfluorene (bp; 130°-135° C./0.2 torr, yield; 18%).

後処理

  1. customIn a 250 ml, three-necked, frame dried
  2. filtrationwere filtered from the organic solution
  3. distillationAfter hexane was distilled
  4. distillationdistilled

出典と根拠

ORDレコード
ord-8c55fb26c72747aeb7123249a869ebe3
出典データセット
uspto-grants-1998_12
特許番号
US05847182

関連ノート

読み込み中…