L-(+)-Cysteine → L-Serine

HRID 1458518ノート

反応式

HRID 1458518 の反応式
[NH2:1][C@H:2]([C:5]([OH:7])=[O:6])[CH2:3]S.[NH2:8][C@H:9]([C:15]([OH:17])=O)CS(=O)(O)=[O:12].[CH:18]([O:20]O)=[O:19]>Cl>[NH2:1][C@H:2]([C:5]([OH:7])=[O:6])[CH2:3][OH:12].[NH2:8][C@H:9]([C:18]([OH:20])=[O:19])[C@@H:15]([CH3:2])[OH:17]

参加物

6

反応物 3

HCID 5862L-(+)-CysteineHCID 66051Performic AcidHCID 72886L-Cysteic acid

生成物 2

HCID 5951L-SerineHCID 6288L-Threonine

試薬・触媒・溶媒 1

HCID 313Hydrochloric Acid溶媒

実験手順

This analysis was conducted after the mutein was hydrolyzed in 6N hydrochloric acid containing 4% thioglycolic acid at 110° C. for 24 hours and 48 hours. Cysteine was quantitated as cysteic acid after performic acid oxidation. The values for serine and threonine were obtained by extrapolating the 0-hour value from the 24- and 48-hour values.

出典と根拠

ORDレコード
ord-da50d835371643ea96da408febaa42c4
出典データセット
uspto-grants-1998_12
特許番号
US05851990

反応ノート

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