Ethyl allyl(2,2-dimethoxyethyl)carbamate → Ethyl allyl(2-oxoethyl)carbamate

HRID 1460747ノート

反応式

HRID 1460747 の反応式
[CH2:1]([N:4]([CH2:10][CH:11](OC)[O:12]C)[C:5](=[O:9])[O:6][CH2:7][CH3:8])[CH:2]=[CH2:3]>C(O)=O>[CH2:1]([N:4]([CH2:10][CH:11]=[O:12])[C:5](=[O:9])[O:6][CH2:7][CH3:8])[CH:2]=[CH2:3]

参加物

3

反応物 1

HCID 10943907Ethyl allyl(2,2-dimethoxyethyl)carbamate

生成物 1

HCID 11084330Ethyl allyl(2-oxoethyl)carbamate

試薬・触媒・溶媒 1

HCID 284Formic Acid溶媒

実験手順

68 g (0.313 mol) of ethyl N-allyl-N-(2,2-dimethoxyethyl) -carbamate are heated at 100° C. for an hour with 150 ml of formic acid. The mixture is poured onto ice, extracted several times with methylene chloride, and the organic phases are washed with sodium hydrogen carbonate solution, dried over magnesium sulphate, concentrated and distilled.

後処理

  1. additionThe mixture is poured onto ice
  2. extractionextracted several times with methylene chloride
  3. washthe organic phases are washed with sodium hydrogen carbonate solution
  4. dry with materialdried over magnesium sulphate
  5. concentrationconcentrated
  6. distillationdistilled

出典と根拠

ORDレコード
ord-fa0da760185d40acb32e26c5e4fe468f
出典データセット
uspto-grants-1991_12
特許番号
US05071999

反応ノート

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