1-Octadecene → HCID 178443003、化合物

HRID 1460923

反応式

HRID 1460923 の反応式
[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[S:19][Cl:20]>>[CH3:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH:2]=[CH2:1].[S:19][Cl:20]

参加物

3

反応物 2

HCID 82171-OctadeceneHCID 15930840CID 15930840

生成物 1

HCID 178443003HCID 178443003、化合物

実験手順

Approximately 840 gm (3.0 mol. 90% purity) of octadecene was charged into a 2-liter reactor equipped with dropping funnel, reflux condenser, thermometer, and mechanical stirrer. Approximately 202.5 gm (1.5 mol.) of sulfur monochloride was added through the dropping funnel. Then the reaction mixture was heated to 95° to 100° C. to activate the sulfochlorination reaction. Moderate exotherm brought the temperature to 113° C. then the reaction was held at 110° C. for four hours. Near the end of the period at 110° C., the color became dark reddish. At completion, the product was left to cool slowly. This produced approximately 103 gm liquid material (C36H72S2Cl2).

後処理

  1. customequipped
  2. temperaturereflux condenser
  3. temperatureThen the reaction mixture was heated to 95° to 100° C.
  4. customthe sulfochlorination reaction
  5. customto 113° C.
  6. customat 110° C.
  7. waitAt completion, the product was left
  8. temperatureto cool slowly

出典と根拠

ORDレコード
ord-d15cfa2e01624d4099d31e6beb1b7543
出典データセット
uspto-grants-1991_12
特許番号
US05073279

関連ノート

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