Triethyloxonium tetrafluoroborate → HCID 21250731、化合物

HRID 1460975ノート

反応式

HRID 1460975 の反応式
[CH3:1][O:2][C:3]1[CH:11]=[CH:10][C:6]([C:7]([NH2:9])=[O:8])=[C:5]([O:12][CH2:13][CH2:14][CH3:15])[CH:4]=1.[F:16][B-:17]([F:20])([F:19])[F:18].[CH2:21]([O+](CC)CC)[CH3:22]>ClCCl>[F:16][B-:17]([F:20])([F:19])[F:18].[CH3:1][O:2][C:3]1[CH:11]=[CH:10][C:6]([C:7](=[NH:9])[O:8][CH2:21][CH3:22])=[C:5]([O:12][CH2:13][CH2:14][CH3:15])[CH:4]=1

参加物

4

反応物 2

HCID 2723982Triethyloxonium tetrafluoroborateHCID 212507054-Methoxy-2-propoxybenzamide

生成物 1

HCID 21250731HCID 21250731、化合物

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

A mixture of 4-methoxy-2-propoxybenzamide (15 g) and triethyloxonium tetrafluoroborate (0.08 mol) in dichloromethane (180 ml) was stirred at ambient temperature for about 60 hours. The reaction mixture was evaporated under reduced pressure and the residue was washed with diethyl ether to yield crude ethyl 4-methoxy-2-propoxybenzimidate tetrafluoroborate, 20.52 g which was used without further purification.

後処理

  1. customThe reaction mixture was evaporated under reduced pressure
  2. washthe residue was washed with diethyl ether

出典と根拠

ORDレコード
ord-61c30f5924514cee9758264589fc0ca4
出典データセット
uspto-grants-1991_12
特許番号
US05073559

反応ノート

読み込み中…