p-(Benzyloxy)nitrobenzene → 4-Benzyloxyaniline
反応式
O.S.[Na].[CH2:4]([O:11][C:12]1[CH:17]=[CH:16][C:15]([N+:18]([O-])=O)=[CH:14][CH:13]=1)[C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1>C(O)C>[CH2:4]([O:11][C:12]1[CH:13]=[CH:14][C:15]([NH2:18])=[CH:16][CH:17]=1)[C:5]1[CH:6]=[CH:7][CH:8]=[CH:9][CH:10]=1参加物
4
実験手順
Sodium hydrogen sulphide monohydrate (40 g) was added to a solution of 4-benzyloxynitrobenzene (25 g) in ethanol (800 ml) and the reaction mixture heated under reflux for four hours. The solvent was removed and the residue was treated with water and extracted into ether. The ether extract was dried and evaporated to give 4-benzyloxyaniline which was purified by extraction with hexane.
後処理
- temperaturethe reaction mixture heated
- temperatureunder reflux for four hours
- customThe solvent was removed
- additionthe residue was treated with water
- extractionextracted into ether
- extractionThe ether extract
- customwas dried
- customevaporated
出典と根拠
- ORDレコード
- ord-1d8f28cc8c3f447fa021280b15636a6a
- 出典データセット
- uspto-grants-1994_04
- 特許番号
- US05302720
反応ノート
読み込み中…