Methanol → HCID 11747608、化合物

反応式

[CH3:1][Si:2]([CH3:13])([CH2:4][Si:5](Cl)([Cl:11])[CH2:6][Si:7]([CH3:10])([CH3:9])[CH3:8])[CH3:3].[CH3:14][OH:15]>>[CH3:1][Si:2]([CH3:13])([CH2:4][Si:5]([Cl:11])([O:15][CH3:14])[CH2:6][Si:7]([CH3:10])([CH3:9])[CH3:8])[CH3:3]

参加物

反応物 2

HCID 887Methanol

HCID 11747735Bis(trimethylsilylmethyl)dichlorosilane

生成物 1

HCID 11747608HCID 11747608、化合物収率 74%

反応条件

温度: 70 °C

実験手順

13.7 g(50 mmoles) of 2,2,6,6-tetramethyl-4,4-dichloro-2,4,6-trisilaheptane were placed in the flask of the same set as Example 1, and then 1.8 g(60 mmoles) of dry methanol were added. The mixture was heated at 70° C. for 2 hrs. The amount of the product was 9.92 g and the yield 74%.

出典と根拠

ORDレコード: ord-b6efa47268994222961eb742258b7bf6
出典データセット: uspto-grants-1994_04
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US05302734

反応ノート

読み込み中…