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Triphenylphosphine → [4-(Benzyloxy)benzyl](triphenyl)phosphonium chloride
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Triphenylphosphine | HCID 11776 | — |
| 反応物 | 4-Benzyloxybenzyl chloride | HCID 70042 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | [4-(Benzyloxy)benzyl](triphenyl)phosphonium chloride | HCID 383834 | 88.1% |
反応手順
To a suspension of 1-(benzyloxy)-4-(chloromethyl)benzene (4.890 g, 21.01 mmol) in toluene (25 ml) was added triphenylphosphine (6.617 g, 25.23 mmol). The mixture was heated under reflux for 24 hrs, and cooled to room temperature. The precipitate was collected by filtration, and dried under reduced pressure to give [4-(benzyloxy)benzyl](triphenyl)phosphonium chloride (9.166 g, yield 88.1%) as a white solid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08999989B2 |
| 出典データセット | uspto-grants-2015_04 |
| ORD ID | ord-813e6d3b514547329678200b2299595c |
| 出典メモ | uspto-grants-2015_04 |