化工社化工社 化学情報印刷レポート · 研究参考用
2-Nitrodiphenylamine → N-Phenyl-o-phenylenediamine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Nitrodiphenylamine | HCID 8407 | — |
| 反応物 | HCID 178418361 | HCID 178418361 | — |
| 触媒 | Palladium | HCID 23938 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | N-Phenyl-o-phenylenediamine | HCID 68297 | — |
反応手順
To a pressure reaction bottle was added 10 g 2-nitrodiphenylamine, 0.5 g 5% palladium on carbon and 100 ml 95% ethanol. The mixture was hydrogenated at 22 C and 40 psi hydrogen for 2 hours. Following filtration through celite and solvent removal, an oil was obtained that crystallized on standing.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US09011734B2 |
| 出典データセット | uspto-grants-2015_04 |
| ORD ID | ord-543b69b6cf424f5ba71a793caa3e2fec |
| 出典メモ | uspto-grants-2015_04 |