Potassium Carbonate → Ethyl 4-(benzyloxy)-3-hydroxybenzoate

HRID 1475729ノート

反応式

HRID 1475729 の反応式
[CH2:1]([O:3][C:4](=[O:23])[C:5]1[CH:10]=[CH:9][C:8]([O:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[C:7]([O:19]C(=O)C)[CH:6]=1)[CH3:2].C(=O)([O-])[O-].[K+].[K+]>CO>[CH2:1]([O:3][C:4](=[O:23])[C:5]1[CH:10]=[CH:9][C:8]([O:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[C:7]([OH:19])[CH:6]=1)[CH3:2]

参加物

4

反応物 2

HCID 11430Potassium CarbonateHCID 67170201HCID 67170201、化合物

生成物 1

HCID 11311797Ethyl 4-(benzyloxy)-3-hydroxybenzoate

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

The compound of step 2 (10 g, 31.8 mmol) was dissolved in methanol, potassium carbonate (88 mg, 0.636 mmol) was added and the mixture was stirred for 2 h under reflux. The solution was evaporated to dryness and the residue used without further purification.

後処理

  1. temperatureunder reflux
  2. customThe solution was evaporated to dryness
  3. customthe residue used without further purification

出典と根拠

ORDレコード
ord-d90752650c4f472285caa383b64c714a
出典データセット
uspto-grants-2015_04
特許番号
US09018383B2

反応ノート

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