Ammonium hexafluorophosphate → HCID 86651392、化合物
反応式
COS([O-])(=O)=O.[CH2:7]([N:9]([CH2:16][CH3:17])[CH:10]=[N+:11]([CH2:14][CH3:15])[CH2:12][CH3:13])[CH3:8].[F:18][P-:19]([F:24])([F:23])([F:22])([F:21])[F:20].[NH4+]>O>[F:18][P-:19]([F:24])([F:23])([F:22])([F:21])[F:20].[CH2:14]([N:11]([CH2:12][CH3:13])[CH:10]=[N+:9]([CH2:16][CH3:17])[CH2:7][CH3:8])[CH3:15]参加物
4
反応条件
- 温度
- 0 °C
実験手順
N,N,N′,N′-Tetraethylformamidinium methylsulfate (4 g) is added to water (25 ml) and the resulting mixture is cooled to 0° C. This mixture is then added to a cooled solution of ammonium hexafluorophosphate (4.9 g) in water (25 ml). The formed precipitate is collected by filtration. The precipitate is then washed with cold water (2×10 ml) and then with diethyl ether (10 ml). Drying in vacuo gives N,N,N′,N′-tetraethylformamidinium hexafluorophosphate (18, R6=Et, R7=Et) as a yellow solid. 1H NMR (DMSO-d6), 7.92 (1H), 3.85-3.54 (8H), 1.45-1.38 (12H).