Dichlorodimethylsilane → Diacetoxydimethylsilane

HRID 1484200ノート

反応式

HRID 1484200 の反応式
[C:1]([O-:4])(=[O:3])[CH3:2].[Na+].[CH3:6][Si:7]([CH3:10])(Cl)Cl>C(OCC)C>[C:1]([O:4][Si:7]([O:4][C:1](=[O:3])[CH3:2])([CH3:10])[CH3:6])(=[O:3])[CH3:2]

参加物

4

反応物 2

HCID 6398DichlorodimethylsilaneHCID 517045Sodium Acetate

生成物 1

HCID 75130Diacetoxydimethylsilane収率 70%

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒2 回

実験手順

To a slurry of sodium acetate (8.2 g, 100 mmol, 2.0 equiv.) in anhydrous diethyl ether (40 mL) was slowly added a solution of dimethyldichloro silane 11A (6.45 g, 50 mmol, 1.0 equiv.) in anhydrous diethyl ether (10 mL). After addition was completed, the mixture was heated at reflux for 2 hours, and then filtered under N2. The filtrate was concentrated under vacuum at 40° C. to give diacetate 11B as a colorless oil (6.1 g, 70%).

後処理

  1. additionAfter addition
  2. temperaturethe mixture was heated
  3. temperatureat reflux for 2 hours
  4. filtrationfiltered under N2
  5. concentrationThe filtrate was concentrated under vacuum at 40° C.

出典と根拠

ORDレコード
ord-044d23d5fb2446ff94e171865cff9bb3
出典データセット
uspto-grants-2016_08
特許番号
US09421273B2

反応ノート

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