反応式
Fc1cc(F)c(F)c(F)c1F>C1=CCCC=CCC1.C1=CCCC=CCC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.COC1CCCC1.C[OH2+].C[OH2+].[Ir].[Ir].c1ccc(N2B(B3Nc4ccccc4N3c3ccccn3)Nc3ccccc32)nc1>CC1(C)OB(c2c(F)c(F)c(F)c(F)c2F)OC1(C)C参加物
6
反応条件
- 温度
- 100 °C
実験手順
The general procedure A was followed using 1,2,3,4,5-pentafluorobenzene (55.4 uL, 0.5 mmol) and B2pin2 (126.9 mg, 0.5 mmol, 1.0 eq.) as starting material. The resulting mixture was allowed to stir 16 hours at 100 oC. 5n was obtained as colorless oil (128.2 mg, 87%) after purification by silica gel flash chromatography (EtOAc/PE=1:10 v/v).
出典と根拠
- ORDレコード
- ord-54534f29ec2f4a67ac86529f28d9ea02
- 出典データセット
- Borylation dataset from Roche
関連ノート
読み込み中…