関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 2-Methyl-7-(trifluoromethyl)quinoline | HCID 22416904 | — |
| 試薬 | Bis(pinacolato)diborane | HCID 2733548 | — |
| 試薬 | 4,4'-Di-tert-butyl-2,2'-bipyridyl | HCID 4249187 | — |
| 触媒 | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| 溶媒 | tert-Butyl methyl ether | HCID 15413 | — |
| 生成物 | HCID 178422399 | HCID 178422399 | 57% |
| 生成物 | HCID 178422497 | HCID 178422497 | 38% |
反応手順
Application of general procedure A to 2-methyl-7-(trifluoromethyl)quinoline (211 mg, 1.00mmol) afforded 2 monoborylated products as a 60:40 ratio.
情報源と証拠
| DOI | 10.1039/c2sc20776a |
|---|
| 出典データセット | Borylation dataset from Roche |
|---|
| ORD ID | ord-297c3aeb46f14a219f8a39f08fe03a57 |
|---|
| 出典メモ | Borylation dataset from Roche |
|---|
