関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 4-Bromothioanisole | HCID 66037 | — |
| 試薬 | 4,4'-Dimethyl-2,2'-bipyridine | HCID 14338 | — |
| 試薬 | Bis(pinacolato)diborane | HCID 2733548 | — |
| 触媒 | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| 溶媒 | P-Xylene | HCID 7809 | — |
| 生成物 | 2-(5-Bromo-2-methylsulfanylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane | HCID 132510261 | 57% |
| 生成物 | HCID 178503104 | HCID 178503104 | 19% |
反応手順
dtbpy: A mixture of ortho- and meta-borylated products (125 mg, 76% yield, ortho/meta + para = 3.0); yellow oil;
情報源と証拠
| DOI | 10.1002/anie.201610041 |
|---|
| 出典データセット | Borylation dataset from Roche |
|---|
| ORD ID | ord-599a909af57c4391868aa64e3ee286a1 |
|---|
| 出典メモ | Borylation dataset from Roche |
|---|
