関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Methyl 3-(methylthio)benzoate | HCID 6432769 | — |
| 試薬 | 4,4'-Dimethyl-2,2'-bipyridine | HCID 14338 | — |
| 試薬 | Bis(pinacolato)diborane | HCID 2733548 | — |
| 触媒 | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| 溶媒 | P-Xylene | HCID 7809 | — |
| 生成物 | HCID 178498626 | HCID 178498626 | 83% |
反応手順
dtbpy: A mixture of ortho- and meta-borylated products (128 mg, 83% yield, ortho/meta + para = <0.01); meta-Isomer 5pwas obtained by further purification by GPC (116 mg, 75% yield), white solid (mp. 115-117 oC)
情報源と証拠
| DOI | 10.1002/anie.201610041 |
|---|
| 出典データセット | Borylation dataset from Roche |
|---|
| ORD ID | ord-76f3f83feb2744bb84a39a38dd5be253 |
|---|
| 出典メモ | Borylation dataset from Roche |
|---|
