Ammonia → HCID 15746509、化合物

反応式

[CH3:1][C:2]1[C:7]([N:8]=[C:9]=[S:10])=[C:6]([N:11]2[CH2:16][CH2:15][O:14][CH2:13][CH2:12]2)[CH:5]=[CH:4][CH:3]=1.[NH3:17]>>[CH3:1][C:2]1[C:7]([NH:8][C:9]([NH2:17])=[S:10])=[C:6]([N:11]2[CH2:16][CH2:15][O:14][CH2:13][CH2:12]2)[CH:5]=[CH:4][CH:3]=1

参加物

反応物 2

HCID 222Ammonia

HCID 18952334HCID 18952334、化合物

生成物 1

HCID 15746509HCID 15746509、化合物

実験手順

Reaction of 6-methyl-2-morpholinophenyl isothiocyanate (8.8 g) with 33% alcoholic ammonia solution (60 ml) at room temperature for 5 hours gave 1-(6-methyl-2-morpholinophenyl)thiourea (9 g) as a pale yellow solid, m.p. 199° C. which was recrystallised from a 1:1 mixture of ethylacetate and hexane.

出典と根拠

ORDレコード: ord-40289cb7c4a2479ab0ab80be106aba0d
出典データセット: uspto-grants-1994_12
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US05373008

反応ノート

読み込み中…