Toluene → 2-Chlorophenyl sulfamate

HRID 1494018

反応式

HRID 1494018 の反応式
[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[OH:8].Cl[S:10]([N:13]=C=O)(=[O:12])=[O:11].C1(C)C=CC=CC=1>C1CCCCC1.C1C=CC=CC=1>[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[O:8][S:10](=[O:12])(=[O:11])[NH2:13]

参加物

5

反応物 3

HCID 1140TolueneHCID 72452-ChlorophenolHCID 70918Chlorosulfonyl isocyanate

生成物 1

HCID 216944982-Chlorophenyl sulfamate収率 59%

試薬・触媒・溶媒 1

HCID 18624872Benzene--cyclohexane (1/1)溶媒

実験手順

This compound was prepared by the procedure used in Example 56. A mixture of 12.8 g (0.1 mole) of 2-chlorophenol, 14.8 g (0.105 mole) of chlorosulfonyl isocyanate and 75 ml of toluene gave 12.2 g (59%) of the title compound as a white solid, mp 62.5°-63.5° C. (cyclohexane-benzene).

後処理

  1. customThis compound was prepared by the procedure

出典と根拠

ORDレコード
ord-bc803db57946496e9e3cf290c4128f56
出典データセット
uspto-grants-1991_06
特許番号
US05025031

関連ノート

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