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2-Amino-1-(2-mercapto-2-methylpropylamino)benzene → 1-[2-(trans-2-Butenylthio)-2-methylpropylamino]-2-(2-mercapto-2-methylpropylamino)benzene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Amino-1-(2-mercapto-2-methylpropylamino)benzene | HCID 10012927 | — |
| 反応物 | 2-(trans-2-Butenylthio)-2-methylpropanal | HCID 10351953 | — |
| 生成物 | 1-[2-(trans-2-Butenylthio)-2-methylpropylamino]-2-(2-mercapto-2-methylpropylamino)benzene | HCID 10020049 | 88.3% |
反応手順
2-Amino-1-(2-mercapto-2-methylpropylamino)benzene (0.36 g, 1.84×10-3 mol) and 0.58 g (3.67×10-3 mol, 200 M %) 2-(trans-2-butenylthio)-2-methylpropanal were reacted by the procedures in Example 2 to give 0.55 g (88% yield) 1-[2-(trans-2-butenylthio)-2-methylpropylamino]-2-(2-mercapto-2-methylpropylamino)benzene as an oil after purification by radial chromatography on a 4 mm silica plate eluting with 100% hexane.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05026913 |
| 出典データセット | uspto-grants-1991_06 |
| ORD ID | ord-44e9e6a07a344ae680c5e5a44a2b4782 |
| 出典メモ | uspto-grants-1991_06 |