化工社化工社 化学情報印刷レポート · 研究参考用
Acetic Acid → 5-Formyl-2-furancarboxylic Acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Acetic Acid | HCID 176 | — |
| 反応物 | 5-Acetoxymethyl-2-furaldehyde | HCID 66349 | — |
| 生成物 | 5-Formyl-2-furancarboxylic Acid | HCID 2793719 | — |
反応手順
5-HMF feed is oxidized with elemental O2 in a multi-step reaction to form FDCA with 5-formyl furan-2-carboxylic acid (FFCA) as a key intermediate eq 1. Oxidation of 5-(acetoxymethyl)furfural (5-AMF), which contains an oxidizable ester and aldehydes moieties, produces FDCA, FFCA, and acetic acid, eq 2. Similarly oxidation of 5-(ethoxymethyl)furfural (5-EMF) produces FDCA, FFCA, 5-(ethoxycarbonyl)furan-2-carboxylic acid (EFCA) and acetic acid, eq 3.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US09206149B2 |
| 出典データセット | uspto-grants-2015_12 |
| ORD ID | ord-b2936e155ffc4c2aa3f6fe5985124084 |
| 出典メモ | uspto-grants-2015_12 |