Aniline → 2-Phenyldibenzo[b,d]thiophene

反応式

N[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C1C2C3C(C=C4C=2C=CC=C4)=CC=CC=3C=C1.C1(C2C3C4=C(C=CCC4=C4C=2C=CC=C4)C=CC=3)C=CC=CC=1.C[C:49]1[CH:61]=[CH:60][C:52]2[S:53][C:54]3[CH:59]=[CH:58][CH:57]=[CH:56][C:55]=3[C:51]=2[CH:50]=1>>[C:2]1([C:57]2[CH:58]=[CH:59][C:54]3[S:53][C:52]4[CH:60]=[CH:61][CH:49]=[CH:50][C:51]=4[C:55]=3[CH:56]=2)[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

参加物

反応物 4

HCID 6115Aniline2 回

HCID 357002-Methyl-dibenzothiophene

HCID 10149107HCID 10149107、化合物

HCID 123339863HCID 123339863、化合物

生成物 1

HCID 135272452-Phenyldibenzo[b,d]thiophene

実験手順

For example, the reaction of aniline with 1H-benzo[de]anthracene of the asphaltene polycyclic core forms the 7-phenyl-1H-benzo[de]anthracene compound as shown (15), and the reaction of aniline with 2-methyldibenzo[b,d]thiophene yields 2-phenyldibenzo[b,d]thiophene (16).