2-(Di-tert-butylphosphino)biphenyl → 9-(4-tert-butylpyridin-2-yl)-2'-(4-phenylpyridin-2-yl)-9H-2,9'-bicarbazole

反応式

[C:1]1([C:7]2[CH:12]=[CH:11][N:10]=[C:9]([C:13]3[CH:25]=[CH:24][C:23]4[C:22]5[C:17](=[CH:18][CH:19]=[CH:20][CH:21]=5)[NH:16][C:15]=4[CH:14]=3)[CH:8]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.Br[C:27]1[CH:39]=[CH:38][C:37]2[C:36]3[C:31](=[CH:32][CH:33]=[CH:34][CH:35]=3)[N:30]([C:40]3[CH:45]=[C:44]([C:46]([CH3:49])([CH3:48])[CH3:47])[CH:43]=[CH:42][N:41]=3)[C:29]=2[CH:28]=1.CC(P(C(C)(C)C)C1C(C2C=CC=CC=2)=CC=CC=1)(C)C.CC([O-])(C)C.[Na+]>C1C=CC(/C=C/C(/C=C/C2C=CC=CC=2)=O)=CC=1.C1C=CC(/C=C/C(/C=C/C2C=CC=CC=2)=O)=CC=1.C1C=CC(/C=C/C(/C=C/C2C=CC=CC=2)=O)=CC=1.[Pd].[Pd]>[C:46]([C:44]1[CH:43]=[CH:42][N:41]=[C:40]([N:30]2[C:29]3[CH:28]=[C:27]([N:16]4[C:15]5[CH:14]=[C:13]([C:9]6[CH:8]=[C:7]([C:1]7[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=7)[CH:12]=[CH:11][N:10]=6)[CH:25]=[CH:24][C:23]=5[C:22]5[C:17]4=[CH:18][CH:19]=[CH:20][CH:21]=5)[CH:39]=[CH:38][C:37]=3[C:36]3[C:31]2=[CH:32][CH:33]=[CH:34][CH:35]=3)[CH:45]=1)([CH3:49])([CH3:47])[CH3:48]