Ethyl Oleate → Methyl Oleate

HRID 1510607

反応式

HRID 1510607 の反応式
[C:1]([O:20][CH2:21]C)(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]>Cl[Ru](=C1N(C2C(C)=CC(C)=CC=2C)CCN1C1C(C)=CC(C)=CC=1C)(Cl)(=CC1C=CC=CC=1)[P](C1CCCCC1)(C1CCCCC1)C1CCCCC1>[C:1]([O:20][CH3:21])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

参加物

3

反応物 1

HCID 5363269Ethyl Oleate

生成物 1

HCID 5364509Methyl Oleate

試薬・触媒・溶媒 1

HCID 178425456HCID 178425456、化合物触媒

反応条件

温度
60 °C

実験手順

A stainless steel autoclave with a glass liner was equipped with a magnetic stirrer bar and charged with ethyl oleate (0.34 g, 1.1 mmol) and Second Generation Grubbs Catalyst (9.3 mg, 0.11 μmol). The autoclave flushed with argon. The autoclave was evacuated and then pressurised with cis-2-butene to a pressure of 15 psi. The autoclave was heated at 60° C. with stirring overnight. The pressure was then released and ethyl vinyl ether (50 μL) added to the reaction mixture. A sample of the product was trans-esterified with methanol by conventional means and analysis of the trans-esterification product by GC showed a conversion of >85% of the oleic chains to 9-undecenoic chains.

後処理

  1. customThe autoclave flushed with argon
  2. customThe autoclave was evacuated
  3. additionethyl vinyl ether (50 μL) added to the reaction mixture

出典と根拠

ORDレコード
ord-86bfe8bceb854c979bf005447f8d093b
出典データセット
uspto-grants-2012_07
特許番号
US08211989B2

関連ノート

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