Ketohydroxy-Estratriene → 3-Hydroxy-13-methyl-16-pyridin-3-ylmethylene-6,7,8,9,11,12,13,14,15,16-decahydro-cyclopenta[a]phenanthren-17-one

反応式

[CH3:31][CH2:32][OH:33].[CH:3]12[CH2:4][CH2:5][C:6]3([CH3:7])[C:8](=[O:9])[CH2:10][CH2:11][CH:12]3[CH:13]1[CH2:14][CH2:15][c:16]1[cH:17][c:18]([OH:19])[cH:20][cH:21][c:22]12.[Na+:2].[OH-:1].[n:23]1[cH:24][c:25]([CH:29]=[O:30])[cH:26][cH:27][cH:28]1>>[CH:3]12[CH2:4][CH2:5][C:6]3([CH3:7])[C:8](=[O:9])[C:10](=[CH:29][c:25]4[cH:24][n:23][cH:28][cH:27][cH:26]4)[CH2:11][CH:12]3[CH:13]1[CH2:14][CH2:15][c:16]1[cH:17][c:18]([OH:19])[cH:20][cH:21][c:22]12