2,4-Dibromoaniline → 1,5-Dibromo-2-(2,4-dimethyl-phenylsulfanyl)-benzene

反応式

[CH3:1][C:2]1[CH:7]=[C:6]([CH3:8])[CH:5]=[CH:4][C:3]=1[SH:9].[Br:10][C:11]1[CH:16]=[C:15]([Br:17])[CH:14]=[CH:13][C:12]=1I.BrC1C=C(Br)C=CC=1N>>[Br:10][C:11]1[CH:16]=[C:15]([Br:17])[CH:14]=[CH:13][C:12]=1[S:9][C:3]1[CH:4]=[CH:5][C:6]([CH3:8])=[CH:7][C:2]=1[CH3:1]

参加物

反応物 3

HCID 120042,4-Dibromoaniline

HCID 836172,4-Dimethylbenzenethiol

HCID 134667252,4-Dibromo-1-iodobenzene

生成物 1

HCID 686846931,5-Dibromo-2-(2,4-dimethyl-phenylsulfanyl)-benzene

実験手順

Prepared from 2,4-dimethyl-benzenethiol and 2,4-dibromo-1-iodo-benzene (prepared from 2,4-dibromo-phenylamine by diazotization according to the general procedure by Tunney and Stille J. Org. Chem. 1987, 52, 748-753).

出典と根拠

ORDレコード: ord-7151fd191b8149959cec8ccb108033bc
出典データセット: uspto-grants-2010_06
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07732463B2

反応ノート

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