Triphenylphosphine → Triphenyl(10-phenyldecyl)phosphonium bromide

HRID 1525799ノート

反応式

HRID 1525799 の反応式
[Br:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1.[C:18]1([P:24]([C:31]2[CH:36]=[CH:35][CH:34]=[CH:33][CH:32]=2)[C:25]2[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=2)[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1>C1(C)C=CC=CC=1>[Br-:1].[C:31]1([P+:24]([C:18]2[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=2)([C:25]2[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=2)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)[CH:32]=[CH:33][CH:34]=[CH:35][CH:36]=1

参加物

4

反応物 2

HCID 11776Triphenylphosphine2 回HCID 27356021-Bromo-10-phenyldecane

生成物 1

HCID 86126936Triphenyl(10-phenyldecyl)phosphonium bromide収率 54.6%

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

反応条件

温度
100 °C

実験手順

Compound 11 (7.0 g) was dissolved in toluene (80 mL) and triphenylphosphine (6.8 g) was added thereto, followed by stirring at 100° C. for 12 hours. Triphenylphosphine (1.3 g) was further added, followed by stirring at 100° C. for 24 hours. After cooling the reaction solution to room temperature, the resulting precipitate was washed with toluene three times and the residue was dried under reduced pressure to obtain the title compound (7.2 g) having the following physical property values.

後処理

  1. stirringby stirring at 100° C. for 24 hours
  2. temperatureAfter cooling the reaction solution to room temperature
  3. washthe resulting precipitate was washed with toluene three times
  4. customthe residue was dried under reduced pressure

出典と根拠

ORDレコード
ord-defc6a76b3924d26a254dcb11cfc59f3
出典データセット
uspto-grants-2015_07
特許番号
US09085523B2

反応ノート

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