3,5-Dinitrosalicylaldehyde → HCID 178449924、化合物

反応式

[N+:1]([C:4]1[C:5]([OH:15])=[C:6]([CH:9]=[C:10]([N+:12]([O-:14])=[O:13])[CH:11]=1)[CH:7]=O)([O-:3])=[O:2].[C:16]([NH:20][OH:21])([CH3:19])([CH3:18])[CH3:17]>>[N+:1]([C:4]1[C:5]([OH:15])=[C:6]([CH:7]=[N+:20]([C:16]([CH3:19])([CH3:18])[CH3:17])[O-:21])[CH:9]=[C:10]([N+:12]([O-:14])=[O:13])[CH:11]=1)([O-:3])=[O:2]

参加物

反応物 2

HCID 755713,5-Dinitrosalicylaldehyde

HCID 98586N-tert-butylhydroxylamine

生成物 1

HCID 178449924HCID 178449924、化合物

実験手順

The title compound was prepared according to the procedure described in Example 13 using 3,5-dinitro-2-hydroxybenzaldehyde and N-tert-butylhydroxylamine. The title compound was isolated in 4.4% yield as a yellow crystalline solid, m.p. 200.3° C. (Rf=0.15 on a silica gel plate using 10:1 EtOAc/MeOH as an eluant).

後処理

customThe title compound was prepared

出典と根拠

ORDレコード: ord-fb98f1652e0e4a8ba384991afd8e2338
出典データセット: uspto-grants-2001_03
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06197826B1

反応ノート

読み込み中…

参加物