化工社化工社 化学情報印刷レポート · 研究参考用
N-bromobutanimide → Methyl 5-(bromomethyl)-2-methoxybenzoate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | N-bromobutanimide | HCID 67184 | — |
| 反応物 | Methyl 2-methoxy-5-methylbenzoate | HCID 10241396 | — |
| 溶媒 | Benzene | HCID 241 | — |
| 生成物 | Methyl 5-(bromomethyl)-2-methoxybenzoate | HCID 19744340 | — |
反応手順
A mixture of 2-methoxy-5-methylbenzoic acid methyl ester (J.Chem.Soc.Perkin Trans.1, 1994, 1125) (1.47 g) and N-bromosuccinimide (1.45 g) in benzene (15 ml) was irradiated under a 500 W halogen lamp for 3 hours. The solvent was evaporated and the residue triturated with diethyl ether. The succinimide was filtered off and the filtrate evaporated.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06200981B1 |
| 出典データセット | uspto-grants-2001_03 |
| ORD ID | ord-cc5a220a1f5644198b9e4917cab8fd4f |
| 出典メモ | uspto-grants-2001_03 |