N1,N1-Dimethyl-N3-(2-nitrophenyl)-1,3-propanediamine → N~1~-[3-(Dimethylamino)propyl]benzene-1,2-diamine

HRID 1532639ノート

反応式

HRID 1532639 の反応式
[CH3:1][N:2]([CH3:16])[CH2:3][CH2:4][CH2:5][NH:6][C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][C:8]=1[N+:13]([O-])=O>C(O)C.[C].[Pd]>[CH3:16][N:2]([CH3:1])[CH2:3][CH2:4][CH2:5][NH:6][C:7]1[C:8]([NH2:13])=[CH:9][CH:10]=[CH:11][CH:12]=1

参加物

4

反応物 1

HCID 210504N1,N1-Dimethyl-N3-(2-nitrophenyl)-1,3-propanediamine

生成物 1

HCID 14174121N~1~-[3-(Dimethylamino)propyl]benzene-1,2-diamine収率 100.1%

試薬・触媒・溶媒 2

HCID 178418390HCID 178418390、化合物触媒HCID 702Ethanol溶媒

実験手順

10% of palladium-carbon (0.18 g) was added to a solution containing N1,N1-dimethyl-N3-(2-nitrophenyl)-1,3-propanediamine (0.90 g) in ethanol (9 ml) and stirred for 2.5 hours under a hydrogen gas atmosphere at room temperature. After the catalyst was removed out by filtration, the filtrate was concentrated, thereby yielding the entitled compound (0.78 g) as reddish brown oil.

後処理

  1. customAfter the catalyst was removed out by filtration
  2. concentrationthe filtrate was concentrated

出典と根拠

ORDレコード
ord-78640b95da544b988deb1b71a3fca6fa
出典データセット
uspto-grants-2001_03
特許番号
US06204264B1

反応ノート

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