Ethylenediamine → N,N''-1,2-Ethanediylbis(urea)

HRID 1535001ノート

反応式

HRID 1535001 の反応式
[CH2:1]([NH2:4])[CH2:2][NH2:3].[N-:5]=[C:6]=[O:7].C([NH+](CC)CC)C.C[N:16]1CCC[C:17]1=[O:21]>>[CH2:1]([NH:4][C:17]([NH2:16])=[O:21])[CH2:2][NH:3][C:6]([NH2:5])=[O:7]

参加物

4

反応物 3

HCID 3301EthylenediamineHCID 13387N-methyl-2-pyrrolidoneHCID 18997612Triethylammonium isocyanate

生成物 1

HCID 74614N,N''-1,2-Ethanediylbis(urea)

実験手順

1.88 g of ethylenediamine (0.031 mol) were added dropwise at room temperature with stirring to 100 ml of a solution of 10 g of triethylammonium isocyanate (0.069 mol) in 100 ml of N-methylpyrrolidone, prepared according to the procedure described in example i. After stirring at room temperature for 24 hours, the reaction mixture was heated to reflux for one hour, the solvent was evaporated and the residue was recrystallized from water. 3.4 g, i.e. 75% of theory, of ethylenediurea were obtained in this way.

後処理

  1. customprepared
  2. temperaturethe reaction mixture was heated
  3. temperatureto reflux for one hour
  4. customthe solvent was evaporated
  5. customthe residue was recrystallized from water

出典と根拠

ORDレコード
ord-36d16dc362974765aa80bd490de8bbfb
出典データセット
uspto-grants-1992_02
特許番号
US05091553

反応ノート

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