Vanadium trichloride oxide → HCID 178514808、化合物
反応式
[O:1]=[V:2].Cl.Cl.Cl.[C:6]1([C:38]2[CH:43]=[CH:42][CH:41]=[CH:40][CH:39]=2)[CH:11]=[CH:10][C:9]([Si:12]([C:26]2[CH:31]=[CH:30][C:29]([C:32]3[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=3)=[CH:28][CH:27]=2)([C:14]2[CH:19]=[CH:18][C:17]([C:20]3[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=3)=[CH:16][CH:15]=2)[OH:13])=[CH:8][CH:7]=1>>[O-2:13].[C:17]1([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[CH:16]=[CH:15][C:14]([Si:12]([C:26]2[CH:31]=[CH:30][C:29]([C:32]3[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=3)=[CH:28][CH:27]=2)([C:9]2[CH:10]=[CH:11][C:6]([C:38]3[CH:39]=[CH:40][CH:41]=[CH:42][CH:43]=3)=[CH:7][CH:8]=2)[O:13][V+2:2]([O:13][Si:12]([C:26]2[CH:31]=[CH:30][C:29]([C:32]3[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=3)=[CH:28][CH:27]=2)([C:9]2[CH:10]=[CH:11][C:6]([C:38]3[CH:39]=[CH:40][CH:41]=[CH:42][CH:43]=3)=[CH:7][CH:8]=2)[C:14]2[CH:15]=[CH:16][C:17]([C:20]3[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=3)=[CH:18][CH:19]=2)[O:1][Si:12]([C:26]2[CH:27]=[CH:28][C:29]([C:32]3[CH:33]=[CH:34][CH:35]=[CH:36][CH:37]=3)=[CH:30][CH:31]=2)([C:14]2[CH:19]=[CH:18][C:17]([C:20]3[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=3)=[CH:16][CH:15]=2)[C:9]2[CH:10]=[CH:11][C:6]([C:38]3[CH:39]=[CH:40][CH:41]=[CH:42][CH:43]=3)=[CH:7][CH:8]=2)=[CH:19][CH:18]=1参加物
3
実験手順
vanadium oxytrichloride is reacted with tri-(p-chlorophenyl)-silanol [m.p. 127°-128°C] to produce tris-[tri-(p-chlorophenyl)-siloxy]vanadium oxide [m.p. 181°C.]; vanadium oxytrichloride is reacted with tri-(p-bromophenyl)-silanol [m.p. 120°-121°C.] to produce the tris-[tri-(p-bromophenyl)-silox]-vanadium oxide [m.p. 175°C.]; and vanadium oxytrichloride is reacted with tri-4-biphenylyl-silanol [m.p. 199°-200°C.] to produce tris-[tri-(4-biphenylyl)-siloxy]-vanadium oxide.
出典と根拠
- ORDレコード
- ord-6acb962f25644d279d700badb246aec7
- 出典データセット
- uspto-grants-1976_09
- DOI