化工社化工社 化学情報印刷レポート · 研究参考用
1-Acetylcyclohexene → 2,3,4,4a,6,7,11b,12,13,13a-decahydro-9,10-dimethoxy-1H-dibenzo[a,f]quinolizin-13-one
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Acetylcyclohexene | HCID 13612 | — |
| 反応物 | 3,4-Dihydroisoquinoline | HCID 76705 | — |
| 反応物 | 1-Acetylcyclopentene | HCID 192925 | — |
| 反応物 | 3,4-Dihydro-6,7-dimethoxyisoquinoline hydrochloride | HCID 2724664 | — |
| 生成物 | 2,3,4,4a,6,7,11b,12,13,13a-decahydro-9,10-dimethoxy-1H-dibenzo[a,f]quinolizin-13-one | HCID 12774492 | — |
反応手順
When in Example 6 appropriate amounts of 3,4-dihydro-6,7 -dimethoxyisoquinoline hydrochloride and 1-cyclohexen-1-yl methyl ketone respectively are substituted for 3,4-dihydroisoquinoline and 1-cyclopenten-1-yl methyl ketone, 2,3,4,4a,6,7,11b,12,13,13a-decahydro-9,10-dimethoxy-1H-dibenzo[a,f]quinolizin-13-one is obtained, M.P. 129°-141°C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US03983122 |
| 出典データセット | uspto-grants-1976_09 |
| ORD ID | ord-b50c4a3134534b4eb5d8e13656d6a958 |
| 出典メモ | uspto-grants-1976_09 |