4-(4-Methoxyphenyl)but-3-en-2-one → HCID 12374368、化合物

HRID 1577040

反応式

HRID 1577040 の反応式
[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[CH3:6][C:7]1[C:15]([CH3:17])([CH3:16])[C:14]2[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=2)[NH+:8]=1.[CH3:18][O:19][C:20]1[CH:25]=[CH:24][C:23]([CH:26]=[CH:27][C:28](=O)[CH3:29])=[CH:22][CH:21]=1>CO>[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[CH3:29][C:28]1[N+:8]2[C:9]3[C:14]([C:15]([CH3:17])([CH3:16])[C:7]=2[CH:6]=[C:26]([C:23]2[CH:22]=[CH:21][C:20]([O:19][CH3:18])=[CH:25][CH:24]=2)[CH:27]=1)=[CH:13][CH:12]=[CH:11][CH:10]=3

参加物

4

反応物 2

HCID 954144-(4-Methoxyphenyl)but-3-en-2-oneHCID 149131883H-Indole, 2,3,3-trimethyl-, perchlorate

生成物 1

HCID 12374368HCID 12374368、化合物

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

2,3,3-Trimethyl-3H-indolium perchlorate (5 g.) and 4-p-methoxyphenylbut-3-ene-2-one (10 g.) were heated together on the steam bath for three hours. The cooled mixture was diluted with methanol and filtered. The product was purified by recrystallization from acetonitrile. Yield 4.1 g.; m.p. 298°-300° .

後処理

  1. filtrationfiltered
  2. customThe product was purified by recrystallization from acetonitrile

出典と根拠

ORDレコード
ord-10a387c8143d4b76b6e143ffaefdfae1
出典データセット
uspto-grants-1976_09
特許番号
US03983288

関連ノート

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