Piperidine → HCID 70576684、化合物

HRID 1577288

反応式

HRID 1577288 の反応式
[I-:1].[CH3:2][N+:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[CH3:9].[CH3:10][O:11][CH:12]([O:23][CH3:24])[CH2:13][O:14][C:15]1[CH:22]=[CH:21][C:18]([CH:19]=O)=[CH:17][CH:16]=1.N1CCCCC1>CO>[I-:1].[CH3:2][N+:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[CH:9]=[CH:19][C:18]1[CH:17]=[CH:16][C:15]([O:14][CH2:13][CH:12]([O:23][CH3:24])[O:11][CH3:10])=[CH:22][CH:21]=1

参加物

5

反応物 3

HCID 8082PiperidineHCID 701071,2-Dimethylpyridinium iodideHCID 20572032HCID 20572032、化合物

生成物 1

HCID 70576684HCID 70576684、化合物収率 70.6%

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

In 50 ml of methanol, 12.7 g of 1,2-dimethylpyridinium iodide and 11.96 g of p-(2,2-dimethoxyethoxy)benzaldehyde were dissolved. The resultant solution, with 1 ml of piperidine added thereto, was refluxed for five hours. The solution was left to cool and the crystals which consequently deposited in the solution were collected through filtration and thoroughly washed with acetone. Consequently, there was obtained 16.30 g of 1-methyl-2[p-(2,2-dimethoxyethoxy)-styryl]pyridinium iodide. In water, this product showed the highest absorption at 360 nm (ε=2.67×104). The infrared absorption spectrum (KBr) of the product showed peaks at 1630, 1615, 1595, 1568, 1512, 1450, 1298, 1260, 1180, 1140, 1073, 965, 862, 821 and 776 cm-1. The yield was 67%.

後処理

  1. temperaturewas refluxed for five hours
  2. waitThe solution was left
  3. temperatureto cool
  4. filtrationwere collected through filtration
  5. washthoroughly washed with acetone

出典と根拠

ORDレコード
ord-72bc878b0a964798bd0c73169da3ba30
出典データセット
uspto-grants-1981_09
特許番号
US04287335

関連ノート

読み込み中…