Bicyclo(2.2.1)heptane-2-carboxylic acid, 3,3-dimethyl- → Camphene

HRID 1577473ノート

反応式

HRID 1577473 の反応式
[CH3:1][C:2]1([CH3:12])[CH:7]2[CH2:8][CH:4]([CH2:5][CH2:6]2)[CH:3]1[C:9](O)=O.C12(C(O)=O)CC(CC1)C(=C)C2(C)C>>[CH:7]12[CH2:8][CH:4]([CH2:5][CH2:6]1)[C:3](=[CH2:9])[C:2]2([CH3:12])[CH3:1]

参加物

3

反応物 2

HCID 99843Bicyclo(2.2.1)heptane-2-carboxylic acid, 3,3-dimethyl-HCID 36374512,2-Dimethyl-3-methylenebicyclo(2.2.1)heptane-1-carboxylic acid2 回

生成物 1

HCID 6616Camphene

実験手順

3.3-Dimethylbicyclo-[2.2.1]-heptane-2-carboxylic acid, further to be called camphenic acid, has been described in Bull. Soc. Chim. France 1972 (no. 12) pages 4770-4777, as an intermediate in the synthesis of the corresponding alcohol. Further the synthesis of this compound has been described in Monatshefte fur Chemie 107, page 945 (1976), wherein is stated that it is an important starting material for the preparation of e.g. bicyclic fragrances. In Nippon Kagaku Zasshi 85, pages 593-597 (1964) it is stated that e.g. camphenic acid can be obtained by oxidation of camphene by peracids; see Chem. Abstr. 62, 11858c (1965).

後処理

  1. customFurther the synthesis of this compound

出典と根拠

ORDレコード
ord-60dc819f6582484897187332c6ebba06
出典データセット
uspto-grants-1981_09
特許番号
US04288349

反応ノート

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