Hydrogen Cyanide → HCID 23344788、化合物

HRID 1579165ノート

反応式

HRID 1579165 の反応式
[C:1]([NH:5][N:6]=[C:7]([CH:9]1[CH2:11][CH2:10]1)[CH3:8])([CH3:4])([CH3:3])[CH3:2].[CH:12]#[N:13]>>[C:1]([NH:5][NH:6][C:7]([C:12]#[N:13])([CH:9]1[CH2:10][CH2:11]1)[CH3:8])([CH3:4])([CH3:2])[CH3:3]

参加物

3

反応物 2

HCID 768Hydrogen CyanideHCID 85772048HCID 85772048、化合物

生成物 1

HCID 23344788HCID 23344788、化合物

実験手順

A solution of 8.7g methyl cyclopropyl ketone t-butylhydrazone in 20 ml liquid hydrocyanic acid was heated for 6 hours in a pressure bottle at 60°C. The solution was cooled, poured into ice water and the aqueous solution extracted twice with ether. The ether extracts were combined, washed with saturated sodium bicarbonate solution, dried over sodium sulfate, filtered and the ether evaporated off. The yield was 10.0g (99%) of a brown liquid. The infrared spectrum was consistent with the structure of the proposed product.

後処理

  1. temperatureThe solution was cooled
  2. extractionthe aqueous solution extracted twice with ether
  3. washwashed with saturated sodium bicarbonate solution
  4. dry with materialdried over sodium sulfate
  5. filtrationfiltered
  6. customthe ether evaporated off

出典と根拠

ORDレコード
ord-260d94e5ef154812a94e6f760bba7180
出典データセット
uspto-grants-1976_01
特許番号
US03931143

反応ノート

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