Bromine → HCID 21567566、化合物

HRID 1579168ノート

反応式

HRID 1579168 の反応式
[C:1]([NH:5][NH:6][C:7]1([C:15]#[N:16])[CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1)([CH3:4])([CH3:3])[CH3:2].BrBr.C(NNC(C#N)(C1CC1)C)(C)(C)C>>[C:1]([N:5]=[N:6][C:7]1([C:15]#[N:16])[CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1)([CH3:4])([CH3:2])[CH3:3]

参加物

4

反応物 3

HCID 24408BromineHCID 21567553HCID 21567553、化合物HCID 23344788HCID 23344788、化合物

生成物 1

HCID 21567566HCID 21567566、化合物

実験手順

1-t-Butylazo-1-cyanocyclooctane was prepared in 93% crude yield by oxidizing 1-t-butylhydrazo-1-cyanocyclooctane with bromine using the same procedure described in Example XIIIC for the oxidation of 1-t-butylhydrazo-1-cyano-1-cyclopropylethane. The crude product was chromatographed over alumina and the product eluted with pentane. The infrared spectrum of the purified product was consistent with the structure of the desired azo. The compound has a 10 hour half-life in trichlorobenzene at approximately 55°C.

後処理

  1. customThe crude product was chromatographed over alumina
  2. washthe product eluted with pentane
  3. customat approximately 55°C.

出典と根拠

ORDレコード
ord-95b94a0eba6743728f8e1cf34313af2e
出典データセット
uspto-grants-1976_01
特許番号
US03931143

反応ノート

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