Bromine → HCID 21567580、化合物

HRID 1579170ノート

反応式

HRID 1579170 の反応式
[C:1]([NH:5][NH:6][C:7]1([C:14]#[N:15])[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1)([CH3:4])([CH3:3])[CH3:2].BrBr.C(NNC(C#N)(C1CC1)C)(C)(C)C>>[C:1]([N:5]=[N:6][C:7]1([C:14]#[N:15])[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1)([CH3:4])([CH3:2])[CH3:3]

参加物

4

反応物 3

HCID 24408BromineHCID 21567558HCID 21567558、化合物HCID 23344788HCID 23344788、化合物

生成物 1

HCID 21567580HCID 21567580、化合物

実験手順

1-t-Butylazo-1-cyanocycloheptane was prepared in 100% crude yield by oxidizing 1-t-butylhydrazo-1-cyanocycloheptane with bromine using the same procedure described in Example XIIIC for the oxidation of 1-t-butylhydrazo-1-cyano-1-cyclopropylethane. The crude product was chromatographed over alumina and the product eluted with pentane. The infrared spectrum of the purified product was consistent with the structure of the desired azo. The compound has a 10 hour half-life in trichlorobenzene at approximately 68°C.

後処理

  1. customThe crude product was chromatographed over alumina
  2. washthe product eluted with pentane
  3. customat approximately 68°C.

出典と根拠

ORDレコード
ord-452db6448fa142be9b0c1d9f0f65a949
出典データセット
uspto-grants-1976_01
特許番号
US03931143

反応ノート

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