Dimethylformamide → 2-(2-Benzoylphenyl)-2-imidazoline

HRID 1579518ノート

反応式

HRID 1579518 の反応式
O.O.O.O.O.O.O.S([O-])([O-])=O.[Na+].[Na+].[O:14]([C:16]1([C:28]2[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=2)[C:24]2[C:19](=[CH:20][CH:21]=[CH:22][CH:23]=2)[C:18]2=[N:25][CH2:26][CH2:27][N:17]12)O.CN(C)C=O>O>[C:16]([C:24]1[CH:23]=[CH:22][CH:21]=[CH:20][C:19]=1[C:18]1[NH:25][CH2:26][CH2:27][N:17]=1)(=[O:14])[C:28]1[CH:29]=[CH:30][CH:31]=[CH:32][CH:33]=1

参加物

5

反応物 3

HCID 6228DimethylformamideHCID 160916Sodium sulfite heptahydrateHCID 214397632,3-dihydro-5-hydroperoxy-5-phenyl-5H-imidazo[2,1-a]isoindole

生成物 1

HCID 124063432-(2-Benzoylphenyl)-2-imidazoline

試薬・触媒・溶媒 1

HCID 962Water溶媒2 回

実験手順

A solution of 0.7 g. of sodium sulfite heptahydrate in 3 ml. of water was added to 0.5 g. of 2,3-dihydro-5-hydroperoxy-5-phenyl-5H-imidazo[2,1-a]isoindole in 7 ml. of dimethylformamide. The solution was heated to 100° for 15 minutes. On cooling and addition of 20 ml. of water, 2-(2-benzoylphenyl)-2-imidazoline was obtained.

後処理

  1. temperatureThe solution was heated to 100° for 15 minutes
  2. temperatureOn cooling
  3. additionaddition of 20 ml

出典と根拠

ORDレコード
ord-6a995959bfc34f67aa8778a57737b695
出典データセット
uspto-grants-1976_01
特許番号
US03931217

反応ノート

読み込み中…