Furan, 2,2'-[oxybis(methylene)]bis- → 2-{[(Furan-2-yl)methoxy]methyl}-5-methylfuran

HRID 1579682ノート

反応式

HRID 1579682 の反応式
[CH2:1]([O:7][CH2:8][C:9]1[O:13][CH:12]=[CH:11][CH:10]=1)[C:2]1[O:6][CH:5]=[CH:4][CH:3]=1.[CH3:14]C1OC(CBr)=CC=1>CCOCC>[CH2:8]([O:7][CH2:1][C:2]1[O:6][C:5]([CH3:14])=[CH:4][CH:3]=1)[C:9]1[O:13][CH:12]=[CH:11][CH:10]=1

参加物

4

反応物 2

HCID 263034Furan, 2,2'-[oxybis(methylene)]bis-HCID 122459262-(Bromomethyl)-5-methylfuran

生成物 1

HCID 205603562-{[(Furan-2-yl)methoxy]methyl}-5-methylfuran

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒

実験手順

d. 5-Methyl-furfuryl furfuryl ether was prepared by the procedure described by J. E. Zanetti in J. Am. Chem. Soc. 49, 1066 (1927) for the difurfuryl ether, starting with 5-methylfurfuryl bromide (Compt. Rend. 222, 1441 (1947)) instead of furfuryl bromide of Zanetti. The product was isolated by ether extraction of the crude mixture after having diluted with water. For purification the ether extract was distilled twice - b.p. 68°-70°C. at 0.01 mm./Hg vacuum. The product was a viscous colourless liquid, darkening rapidly on contact with air.

出典と根拠

ORDレコード
ord-77656f0e55c94a0984a1a173358a35a8
出典データセット
uspto-grants-1976_01
特許番号
US03931245

反応ノート

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